Synthesis and Characterization of New Chiral Monoanionic [ON] Ancillary Phenolate Ligands

Binda, Pascal and Glover, Leslie (2014) Synthesis and Characterization of New Chiral Monoanionic [ON] Ancillary Phenolate Ligands. International Journal of Organic Chemistry, 04 (03). pp. 182-188. ISSN 2161-4687

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Official URL: https://doi.org/10.4236/ijoc.2014.43020

Abstract

Three new chiral monoanionic [ON] ancillary phenolate ligands with varying pendant arms have been synthesized in moderate to high yields (50% - 85%) via Mannich-type condensation reaction of chiral substituted phenol, formaldehyde and (+)-bis-[(R)-1-phenylethyl]amine. These new organic compounds were fully characterized via nuclear magnetic resonance spectroscopy (1H and 13C) and elemental analysis. The newly synthesized ligands are suitable candidates for metal-catalyzed ring-opening of lactones and asymmetric catalysis.

Item Type:	Article
Subjects:	European Repository > Chemical Science
Depositing User:	Managing Editor
Date Deposited:	16 Jan 2023 06:16
Last Modified:	22 Sep 2023 08:00
URI:	http://go7publish.com/id/eprint/1504

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